What is Gibbs Free Energy – Definition

In thermodynamics, the Gibbs free energy is a thermodynamic potential that is defined as the enthalpy of the system minus the product of the temperature times the entropy of the system. Periodic Table

Gibbs Free Energy

In thermodynamics, the Gibbs free energy is a thermodynamic potential that is defined as the enthalpy of the system minus the product of the temperature times the entropy of the system. Since the enthalpy is defined to be the sum of the internal energy E plus the product of the pressure p and volume V, the Gibbs free energy is defined as:

gibbs free energy - equation

The change in Gibbs free energy, ΔG, in chemistry, is a very useful parameter. It can be thought of as the maximum amount of work obtainable from a reaction.

gibbs free energy
Thermodynamic Potentials; the term Ts represents the energy you can get from the system’s environment by heating; the term pV represents the expansion work.
 
References:
Nuclear and Reactor Physics:
  1. J. R. Lamarsh, Introduction to Nuclear Reactor Theory, 2nd ed., Addison-Wesley, Reading, MA (1983).
  2. J. R. Lamarsh, A. J. Baratta, Introduction to Nuclear Engineering, 3d ed., Prentice-Hall, 2001, ISBN: 0-201-82498-1.
  3. W. M. Stacey, Nuclear Reactor Physics, John Wiley & Sons, 2001, ISBN: 0- 471-39127-1.
  4. Glasstone, Sesonske. Nuclear Reactor Engineering: Reactor Systems Engineering, Springer; 4th edition, 1994, ISBN: 978-0412985317
  5. W.S.C. Williams. Nuclear and Particle Physics. Clarendon Press; 1 edition, 1991, ISBN: 978-0198520467
  6. G.R.Keepin. Physics of Nuclear Kinetics. Addison-Wesley Pub. Co; 1st edition, 1965
  7. Robert Reed Burn, Introduction to Nuclear Reactor Operation, 1988.
  8. U.S. Department of Energy, Nuclear Physics and Reactor Theory. DOE Fundamentals Handbook, Volume 1 and 2. January 1993.

Advanced Reactor Physics:

  1. K. O. Ott, W. A. Bezella, Introductory Nuclear Reactor Statics, American Nuclear Society, Revised edition (1989), 1989, ISBN: 0-894-48033-2.
  2. K. O. Ott, R. J. Neuhold, Introductory Nuclear Reactor Dynamics, American Nuclear Society, 1985, ISBN: 0-894-48029-4.
  3. D. L. Hetrick, Dynamics of Nuclear Reactors, American Nuclear Society, 1993, ISBN: 0-894-48453-2.
  4. E. E. Lewis, W. F. Miller, Computational Methods of Neutron Transport, American Nuclear Society, 1993, ISBN: 0-894-48452-4.

See also:

Energy

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